Green synthesis of nickel ferrite nanoparticles using starch for visible-light photocatalytic degradation of crystal violet
Từ khóa
DOI:
https://doi.org/10.26459/hueunijns.v134i1S-1.7850Tóm tắt
This study presents the green synthesis of NiFe₂O₄ nanoparticles with starch as a reducing and stabilising agent. The material was characterised with XRD, FT-IR, SEM, TEM, BET, and UV–Vis DRS, confirming a spinel structure, mesoporosity (58.3 m²/g), uniform spherical morphology (10–20 nm), and a band gap of 2.54 eV. Photocatalytic degradation of crystal violet under visible light achieved a 76.0% efficiency within 120 minutes, following pseudo-first-order kinetics. Compared with other photocatalysts, NiFe₂O₄ exhibits superior activity. The starch-mediated green synthesis improved dispersion and photocatalytic performance, offering a sustainable route for efficient visible-light-driven photocatalysts in environmental remediation.Lượt tải
Tài liệu tham khảo
1. Irshad Z, Bibi I, Ghafoor A, Majid F, Kamal S, Ezzine S, et al. Ni doped SrFe12O19 nanoparticles synthesised via micro-emulsion route and photocatalytic activity evaluation for the degradation of crystal violet under visible light irradiation. Results Phys. 2022;42:106006.
2. Komal, Srivastava RC, Joshi CS, Verma HK. Zinc oxide and nickel ferrite nanocomposite as an efficient photocatalyst for crystal violet dye degradation. Solid State Commun. 2024; 386:115517.
3. Ahmad W, Khan A, Ali N, Khan S, Uddin S, Malik S, et al. Photocatalytic degradation of crystal violet dye under sunlight by chitosan-encapsulated ternary metal selenide microspheres. Environ Sci Pollut Res. 2021;28(7):8074-87.
4. Shende TP, Bhanvase BA, Rathod AP, Pinjari D V, Sonawane SH. Sonochemical synthesis of Graphene-Ce-TiO2 and Graphene-Fe-TiO2 ternary hybrid photocatalyst nanocomposite and its application in degradation of crystal violet dye. Ultrason Sonochem. 2018;41:582-9.
5. Katubi KM, Aslam A, Khalil S, Alrowaili ZA, Al-Buriahi MS, Anwar M, et al. Synthesis and characterisation of graphitic carbon nitride composite with NiFe2O4/CdO for photocatalytic treatment of diclofenac sodium and crystal violet. Opt Mater (Amst). 2023;139:113721.
6. Farooq A, Alzahrani FMA, Alomayrah N, Manzoor A, Alrowaili ZA, Al-Buriahi MS, et al. Solar light driven enhanced photocatalytic efficiency of Graphene based composite of co-doped Bismuth Ferrite (Ba0.5 Bi0.5 Nd0.5 Fe1.5 O3/Gr0.375) for Crystal Violet and Paracetamol. Curr Appl Phys. 2024; 63:126-35.
7. Khan I, Saeed K, Zekker I, Zhang B, Hendi AH, Ahmad A, et al. Review on Methylene Blue: Its Properties, Uses, Toxicity and Photodegradation. Water. 2022;14(2):242.
8. Khalil LB, Rophael MW, Mourad WE. The removal of the toxic Hg(II) salts from water by photocatalysis. Appl Catal B Environ. 2002; 36(2):125-30.
9. Rao R, Zhang X, Sun X, Wang M, Ma Y. Effects of elemental chemical state in NiFe2O4@ TiO2 on the photocatalytic performance. J Wuhan Univ Technol Sci Ed. 2020;35(2):320-6.
10. Jihad KM, Roknabadi MR, Mohammadi M, Goharshadi EK. Reduced graphene oxide/TiO2/NiFe2O4 nanocomposite as a stable photocatalyst and strong antibacterial agent. Sustain Environ Res. 2023;33(1).
11. Zhao DF, Yang H, Li RS, Ma JY, Feng WJ. Fabrication of nickel ferrite–graphene nanocomposites and their photocatalytic properties. Mater Res Innov. 2014;18(7):519-23.
12. Zhang H, Xia B, Wang P, Wang Y, Li Z, Wang Y, et al. From waste to waste treatment: mesoporous magnetic NiFe2O4/ZnCuCr-layered double hydroxide composite for wastewater treatment. J Alloys Compd. 2020;819:153053.
13. Karunakaran G, Jagathambal M, Van Minh N, Kolesnikov E, Kuznetsov D. Green Synthesis of NiFe2O4 Spinel-Structured Nanoparticles Using Hydrangea paniculata Flower Extract with Excellent Magnetic Property. JOM. 2018;70(7):1337-43.
14. Xiang W, Hernandez S, Hosseini P, Bai F, Hagemann U, Heidelmann M, et al. Unveiling Surface Species Formed on Ni-Fe Spinel Oxides During the Oxygen Evolution Reaction at the Atomic Scale. Adv Sci. 2025;2501967.
15. Adeleke JT, Theivasanthi T, Thiruppathi M, Swaminathan M, Akomolafe T, Alabi AB. Photocatalytic degradation of methylene blue by ZnO/NiFe2O4 nanoparticles. Appl Surf Sci. 2018;455:195-200.
16. Wang Y, Wang H, Yang Y, Xin B. Magnetic NiFe2O4 3D nanosphere photocatalyst: Glycerol-assisted microwave solvothermal synthesis and photocatalytic activity under microwave electrodeless discharge lamp. Ceram Int. 2021; 47(10):14594-602.
17. Taqvi SIH, Solangi AR, Buledi JA, Khand NH, Junejo B, Memon AF, et al. Plant extract-based green fabrication of nickel ferrite (NiFe2O4) nanoparticles: An operative platform for non-enzymatic determination of pentachlorophenol. Chemosphere. 2022;294:133760.
18. Tong SK, Chi PW, Kung SH, Wei DH. Tuning bandgap and surface wettability of NiFe2O4 driven by phase transition. Sci Rep. 2018;8(1):1338.
19. Bhosale S V, Kanhe NS, Bhoraskar S V, Bhat SK, Bulakhe RN, Shim JJ, et al. Micro-structural analysis of NiFe2O4 nanoparticles synthesised by thermal plasma route and its suitability for BSA adsorption. J Mater Sci Mater Med. 2015;26:1-15.
20. Ashery A, Zawrah M, Abou Hammad AB, El-Okr MM, Zawrah MF, Abou Hammad AB. Structural and Magnetic Analysis on Spinel (NiFe2O4) Prepared By Sol Gel Process at Different Calcinations Temperatures. Artic IOSR J Appl Phys. 2016;8(3):15-9.
21. Moradi-Bieranvand M, Farhadi S, Zabardasti A, Mahmoudi F. Construction of magnetic MoS2/NiFe2O4/MIL-101(Fe) hybrid nanostructures for separation of dyes and antibiotics from aqueous media. RSC Adv. 2024;14(16):11037-56.
22. Massoudinejad M, Rasoulzadeh H, Ghaderpoori M. Magnetic chitosan nanocomposite: fabrication, properties, and optimization for adsorptive removal of crystal violet from aqueous solutions. Carbohydr Polym. 2019;206:844-53.
23. Eisavi R, Ghadernejad S. NiFe2O4@SiO2–Cu as a novel and efficient magnetically recoverable nanocatalyst for regioselective synthesis of β-thiol-1, 2, 3-triazoles under benign conditions. RSC Adv. 2023;13(40):27984-96.
24. Zahra S, Naz U, Irshad M, Sheikh A, Zahra S. Effect of calcination temperature on structural and magnetic properties of polypropylene glycol stabilised nickel ferrite nanoparticles. BMC Chem. 2025;19(1):106.
25. Kumar P V, Short MP, Yip S, Yildiz B, Grossman JC. High surface reactivity and water adsorption on NiFe2O4 (111) surfaces. J Phys Chem C. 2013; 117(11):5678-83.
26. Tavakoli-Azar T, Mahjoub A, Sadjadi MS, Ghaznavi-Ghoushchi MB. Enhanced photocatalytic activity of ZrO2-CdZrO3-S nanocomposites for degradation of Crystal Violet dye under sunlight. J Photochem Photobiol A Chem. 2022;426:113746.
