Crystalline Perovskite La<sub> 0.67-x</sub>Li<sub> 3x </sub> TiO <sub> 3</sub>: Preparation and Ionic Conducting Characterization

  • Nguyen Nang Dinh
  • Pham Duy Long
  • Le Dinh Trong

Abstract

Crystalline perovskite La0.67-xLi 3x TiO 3 with x = 0.06, 0.11 and 0.15 were prepared by solid-state-solution reactions at 1350 0 C from TiO 2 , La 2 O 3 and Li 2 CO 3 Crystalline structure of these compounds was analyzed by XRD method. The ionic conducting property of La 0.67-x Li 3xTiO 3 was characterized on AutoLab. Potentiostat-PGS30 system with impedance technique using fitting software program available in the equipment. The highest ion conductivity at room temperature was found for the compound with x =0.11, namely $\sigma$ = 3.1 x 10 -5Scm -1. With increase of temperature the ionic conductivity increased and at 2000C it reached a value in two orders in magnitude higher (6 x 10 -3Scm -1). The activation energy of the compounds was determined on Ln($\sigma$) vs. 1/T plots and found to be as low as 0.36 eV.

Tác giả

Nguyen Nang Dinh
Journals of Science 70 Tran Hung Dao Str, Hanoi, Vietnam
Pham Duy Long
Institute of Materials Science, VAST
Le Dinh Trong
Faculty of Physics, Hanoi Pedagogical University No. 2
điểm /   đánh giá
Published
2007-09-07
Section
Articles