A novel method for synthesizing ZIF-14 from zinc acetate dihydrate in methanol without additional substances
DOI:
https://doi.org/10.62239/jca.2026.019Abstract
This paper presents a novel method for synthesizing ZIF-14 from zinc acetate dihydrate in methanol solvent without additional substances. Accordingly, the research results demonstrated that in a reaction environment containing only methanol solvent, with a suitable crystallization regime, pure ZIF-14 was formed. Under the experimental conditions, the absence of an alkaline additional substance still allowed for the removal of H+ from HeIM, promoting the formation of Zn–eIM–Zn bonds to create the ZIF-14 structure. ZIF-14 was formed with crystallinity of 100 %, a particle size of 400 nm (SEM), a specific surface area of 513 m2/g (BET), and a synthesis yield of 60.2 %.Downloads
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