Removal of polystyrene (PS) microplastics using a magnetic Fe₃O₄@MIL-101(Cr) composite
DOI:
https://doi.org/10.62239/jca.2026.017Abstract
In this study, a Fe₃O₄@MIL-101(Cr) composite material was synthesized through a simple approach combining Fe₃O₄ and MIL-101(Cr), using waste PET as the raw material source. The obtained composite exhibited magnetic properties with a saturation magnetization of approximately 18 emu g⁻¹, compared with 50 emu g⁻¹ for pure Fe₃O₄. The synthesized materials were then employed as adsorbents for the removal of polystyrene (PS) microplastics from aqueous environments. The experimental results showed that under optimal conditions (pH = 8.15, room temperature, and an adsorbent dosage of Fe₃O₄@MIL-101(Cr) of 1.25 g L⁻¹), the removal efficiency of PS reached approximately 91.4 ± 3.74% after 150 min of interaction. Furthermore, the Fe₃O₄@MIL-101(Cr) composite could be easily recovered using an external magnetic field, demonstrating its potential as an environmentally friendly and recyclable adsorbent for the treatment of microplastic contamination in aquatic environments.Downloads
References
P. Holm, G. Schulz, K. Athanasopulu, Biol. Unserer Zeit, 43(1) (2013) 27–33. https://doi.org/10.1002/biuz.201310497
M. Darabi, M.R. Khosravi-Darani, A.A. Mohammadi, Springer, Cham (2021) 109–126. https://doi.org/10.1007/978-3-030-86879-7_5
S. Mishra, A.P. Das, Wastewater Treatment: Cutting-Edge Molecular Tools, Techniques and Applied Aspects, Elsevier (2021) 237–251. https://doi.org/10.1016/B978-0-12-821881-5.00011-8
D.K.A. Barnes, F. Galgani, R.C. Thompson, M. Barlaz, Philos. Trans. R. Soc. B Biol. Sci., 364(1526) (2009) 1985–1998. https://doi.org/10.1098/rstb.2008.0205
Y. Picó, D. Barceló, ACS Omega, 4(4) (2019) 6709–6719. https://doi.org/10.1021/acsomega.9b00222
K. Duis, A. Coors, Environ. Sci. Eur., 28 (2016) 1–25. https://doi.org/10.1186/s12302-016-0085-9
J. Barrett, A. Chase, C. Zhang, S. Hollands, P. Sutton, Front. Mar. Sci., 7 (2020) 576170. https://doi.org/10.3389/fmars.2020.576170
Y. Liu, W. Guo, X. Wang, S. Liu, Y. Liu, J. Hazard. Mater., 421 (2022) 126700. https://doi.org/10.1016/j.jhazmat.2021.126700
J. Ma, Y. Wang, J. Liu, H. Zhu, Y. Wang, Chemosphere, 307 (2022) 135749. https://doi.org/10.1016/j.chemosphere.2022.135749
M. Kaykhaii, M.R. Abolghasemi, R. Khosravi, A. Ebrahimi, Ind. Eng. Chem. Res., 62(9) (2023) 3835–3843. https://doi.org/10.1021/acs.iecr.2c04418
Y.-J. Chen, Y.-T. Li, J.-H. Kim, H.-S. Kim, D.-H. Kim, J. Mater. Chem. A, 8(29) (2020) 14644–14652. https://doi.org/10.1039/D0TA03829K
K.A. Adegoke, A. Alabi, O. Adebayo, S.A. Aderibigbe, Mar. Pollut. Bull., 187 (2023) 114546. https://doi.org/10.1016/j.marpolbul.2022.114546
G. Gnanasekaran, M. Saravanakumar, N.R. Babu, T. Arumugam, Sep. Purif. Technol., 277 (2021) 119655. https://doi.org/10.1016/j.seppur.2021.119655
A.A. Mohana, M. Yaseen Al-Gheethi, A. Al-Hashmi, A. Al-Khadhuri, Chemosphere, 309 (2022) 136682. https://doi.org/10.1016/j.chemosphere.2022.136682
X.N. Pham, V.-T. Vu, V.T.H. Nguyen, T.-T.-B. Nguyen, H.V. Doan, Nanoscale Adv., 4 (2022) 3600–3608. https://doi.org/10.1039/d2na00371f
V.T.H. Nguyen, T.T.-B. Nguyen, H.T. Nguyen, X.N. Pham, ChemNanoMat, 12 (2026) e202500677. https://doi.org/10.1002/cnma.202500677
X.-N. Pham, H.-H. Nguyen, H.T. Nguyen, T.T.-B. Nguyen, Chem. Eng. Technol., 48 (2026) e70135. https://doi.org/10.1002/ceat.70135
E. Bianchetti, C. Di Valentin, J. Phys. Chem. Lett., 13 (2022) 9348–9354. https://doi.org/10.1021/acs.jpclett.2c02186
H. Wan, J. Wang, X. Sheng, J. Yan, W. Zhang, Y. Xu, Toxics, 10 (2022) 70. https://doi.org/10.3390/toxics10020070
X. Shi, X. Zhang, W. Gao, Y. Zhang, D. He, Sci. Total Environ., 802 (2022) 149838. https://doi.org/10.1016/j.scitotenv.2021.149838
N. Singh, N. Khandelwal, Z.A. Ganie, E. Tiwari, G.K. Darbha, Chem. Eng. J., 418 (2021) 129405. https://doi.org/10.1016/j.cej.2021.129405
C. Shi, S. Zhang, J. Zhao, J. Ma, H. Wu, H. Sun, S. Cheng, Sep. Purif. Technol., 288 (2022) 120564. https://doi.org/10.1016/j.seppur.2022.120564









